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CodeVID-P11-11-TEF-01
Thermal Equilibrium & the First Law — Assignment
Chapter: Thermodynamics
Topic: Thermal Equilibrium & the First Law
Maximum Marks: 30
Time: 60 minutes
Name: ____________________ Roll No.: __________ Date: ____________

General Instructions

  • All questions are compulsory.
  • Section A carries 1 mark each, Section B 2 marks, Section C 3 marks and Section D 5 marks.
  • Show all working for Sections B, C and D. Only final answers are given at the end — for full solutions, raise your doubts with your teacher.
Section A — Multiple Choice Questions 5 × 1 = 5 marks
1.
The first law of thermodynamics is written as:
  • A.$\Delta Q=\Delta U-\Delta W$
  • B.$\Delta Q=\Delta U+\Delta W$
  • C.$\Delta W=\Delta U+\Delta Q$
  • D.$\Delta U=\Delta Q+\Delta W$
2.
For an ideal gas, internal energy depends only on:
  • A.pressure
  • B.volume
  • C.temperature
  • D.density
3.
In a cyclic process the change in internal energy is:
  • A.maximum
  • B.zero
  • C.negative
  • D.equal to the heat absorbed
4.
Work done by a gas is positive when the gas:
  • A.is compressed
  • B.expands
  • C.is cooled
  • D.is heated at fixed volume
5.
The quantity that is NOT a state function is:
  • A.temperature
  • B.internal energy
  • C.pressure
  • D.heat
Section B — Short Answer (2 marks) 3 × 2 = 6 marks
6.
State the zeroth law of thermodynamics.
7.
A gas absorbs 300 J of heat and its internal energy rises by 120 J. Find the work done by the gas.
8.
Why are heat and work not state functions?
Section C — Short Answer (3 marks) 2 × 3 = 6 marks
9.
Derive the expression for the work done by a gas during a small volume change and write the general formula.
10.
A gas is taken around a cycle and absorbs a net 250 J of heat. Find the net work done and explain.
Section D — Long Answer (5 marks) 1 × 5 = 5 marks
11.
State the first law of thermodynamics, explain the sign convention for $\Delta Q$, $\Delta U$ and $\Delta W$, and apply it to (i) an isothermal change and (ii) a cyclic process.

Answer Key

Section A — Multiple Choice Questions
  1. (B) $\Delta Q=\Delta U+\Delta W$
  2. (C) temperature
  3. (B) zero
  4. (B) expands
  5. (D) heat
Section B — Short Answer (2 marks)
  1. If A is in thermal equilibrium with C and B is in equilibrium with C, then A and B are in equilibrium with each other; this defines temperature.
  2. $\Delta W=\Delta Q-\Delta U=300-120=180\ \text{J}$.
  3. Their values depend on the path taken between two states, not only on the initial and final states.
Section C — Short Answer (3 marks)
  1. For a piston of area $A$ moving $dx$, force $=PA$, so $dW=PA\,dx=P\,dV$; for a finite change $W=\int_{V_1}^{V_2}P\,dV$, the area under the $P$–$V$ curve.
  2. For a cycle $\Delta U=0$, so $\Delta W=\Delta Q=250\ \text{J}$; the net work equals the area enclosed by the loop on a $P$–$V$ diagram.
Section D — Long Answer (5 marks)
  1. $\Delta Q=\Delta U+\Delta W$. $\Delta Q>0$ if heat is added, $\Delta W>0$ if the gas does work, $\Delta U>0$ if temperature rises. (i) Isothermal: $\Delta U=0$, so $\Delta Q=\Delta W$. (ii) Cyclic: $\Delta U=0$, so $\Delta Q=\Delta W$ = area enclosed by the loop.
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