The magnetic moment of a transition metal ion is $\sqrt{24}$ B.M. How many unpaired electrons does it have?
The magnetic moment of a transition metal ion is $\sqrt{24}$ B.M. How many unpaired electrons does it have?
1 Answer
VAVidaara Admin
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· 2mo ago
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Using spin-only formula:
$$\mu = \sqrt{n(n+2)} B.M.$$
$$\sqrt{n(n+2)} = \sqrt{24} \Rightarrow n(n+2) = 24 \Rightarrow n^2+2n-24 = 0$$
$$n = \frac{-2 + \sqrt{4+96}}{2} = \frac{-2+10}{2} = 4 unpaired electrons$$
(e.g., $Fe^{2+}$: $[Ar] 3d^6$ with 4 unpaired electrons in high-spin)
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Discussion (4)
GP
For revision — the key formula used here comes up almost every year.
J
Can someone explain why we ignore the other root here?
L
I solved it a slightly different way and got the same answer, good sign.
KS
Pro tip: memorise the standard result, it reappears in many problems.