JEE chemistry

Why does the -OH group activate the benzene ring and direct substituents to ortho/para positions — JEE Chemistry

RVRohit Verma · 10 Asked 16d ago 1,166 views 1 answer

Why does the $-OH$ group activate the benzene ring and direct substituents to ortho/para positions?

1 Answer

KKavyaSharma27 ✓ Accepted · 14d ago ▲ 8

The lone pairs on the O atom of $-OH$ are donated into the ring by resonance, creating negative charge at ortho and para positions:

$$Resonance structures increase electron density at o- and p-positions$$

Since electrophiles attack at positions of high electron density:

$$-OH is an ortho/para director and ring activator$$

Compared to $-NO_2$ which withdraws electrons by resonance and is a deactivating meta director.

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Discussion (4)

DM
Underrated solution. The way you set it up makes it almost obvious.
Divya Mehta · 14d ago
S
Adding for context: NCERT covers the base concept in the same chapter.
SitaKhadka16 · 13d ago
SP
Is there a faster shortcut for this in the actual exam? Time is tight.
Suresh Pillai · 12d ago
MT
Plotting it roughly also helps you sanity-check the sign.
Manish Tiwari · 12d ago
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