IMO Practice Test — Thermodynamics
12 Questions • 15 min • Olympiad level
15:00
Question 1 of 12
A gas does 50 J of work in an isothermal expansion and 40 J in an adiabatic expansion between the same volumes. In the adiabatic case the internal energy change is:
$+40\ \text{J}$
$-40\ \text{J}$
$0$
$-50\ \text{J}$
Explanation: Adiabatic: $\Delta Q=0$, so $\Delta U=-\Delta W=-40\ \text{J}$.
Question 2 of 12
A monatomic gas ($\gamma=5/3$) is compressed adiabatically to one-eighth of its volume. The temperature becomes (from $T$):
$2T$
$4T$
$8T$
$\frac{T}{4}$
Explanation: $T_2=T(V_1/V_2)^{\gamma-1}=T\cdot8^{2/3}=4T$.
Question 3 of 12
The slope of the adiabatic curve to the isothermal curve at a point is in the ratio:
$1:\gamma$
$\gamma:1$
$1:1$
$\gamma^2:1$
Explanation: Adiabatic slope $=\gamma P/V$, isothermal slope $=P/V$, ratio $\gamma:1$.
Question 4 of 12
A Carnot engine has efficiency 40%. If the sink temperature is lowered by 50 K keeping the source fixed, the efficiency becomes 50%. The source temperature is:
$500\ \text{K}$
$400\ \text{K}$
$600\ \text{K}$
$250\ \text{K}$
Explanation: $T_2/T_1=0.6$ and $(T_2-50)/T_1=0.5$, so $50/T_1=0.1$, giving $T_1=500\ \text{K}$.
Question 5 of 12
A Carnot engine and a Carnot refrigerator work between the same two temperatures. If the engine's efficiency is $\eta$, the refrigerator's COP is:
$\eta$
$\frac{1}{\eta}$
$\frac{1-\eta}{\eta}$
$1-\eta$
Explanation: $\eta=1-T_2/T_1$ and $\beta=\frac{T_2}{T_1-T_2}=\frac{1-\eta}{\eta}$.
Question 6 of 12
For one mole of an ideal gas, $C_v=\frac{5}{2}R$. The value of $\gamma$ is:
$1.67$
$1.40$
$1.33$
$1.50$
Explanation: $C_p=C_v+R=\frac{7}{2}R$, so $\gamma=\frac{7/2}{5/2}=1.4$.
Question 7 of 12
Heat $Q$ is supplied to a diatomic gas ($\gamma=1.4$) at constant pressure. The fraction used to do work is:
$\frac{2}{7}$
$\frac{5}{7}$
$\frac{1}{2}$
$\frac{2}{5}$
Explanation: $\frac{W}{Q}=\frac{R}{C_p}=\frac{\gamma-1}{\gamma}=\frac{0.4}{1.4}=\frac{2}{7}$.
Question 8 of 12
An ideal refrigerator transfers 600 J of heat to a 300 K room using 100 J of work. The temperature of the cold interior is:
$250\ \text{K}$
$240\ \text{K}$
$260\ \text{K}$
$200\ \text{K}$
Explanation: $Q_2=Q_1-W=500\ \text{J}$; $\beta=Q_2/W=5=\frac{T_2}{T_1-T_2}$, so $T_2=5(300-T_2)\Rightarrow T_2=250\ \text{K}$.
Question 9 of 12
In a cyclic process the area enclosed by the loop on a $P$–$V$ diagram represents:
the change in internal energy
the net heat absorbed and net work done
the entropy change
zero
Explanation: For a cycle $\Delta U=0$, so net heat = net work = area of the loop.
Question 10 of 12
Two Carnot engines operate in series: the first between 800 K and $T$, the second between $T$ and 200 K, with equal efficiencies. Then $T$ is:
$500\ \text{K}$
$400\ \text{K}$
$600\ \text{K}$
$300\ \text{K}$
Explanation: Equal efficiency means $\frac{T}{800}=\frac{200}{T}$, so $T^2=160000$, $T=400\ \text{K}$.
Question 11 of 12
It is impossible to convert heat completely into work in a cyclic process. This is a statement of:
the zeroth law
the first law
the second law
Mayer's relation
Explanation: This is the Kelvin–Planck form of the second law of thermodynamics.
Question 12 of 12
A gas expands so that $PV^{1.4}=\text{const}$ and also is thermally insulated. If its volume doubles, the pressure becomes (from $P$):
$P/2$
$P\cdot2^{1.4}$
$P/2^{1.4}$
$2P$
Explanation: $P_2=P_1(V_1/V_2)^{1.4}=P/2^{1.4}$.