Distinguish between addition and condensation polymerization with one example each — JEE Chemistry
Distinguish between addition and condensation polymerization with one example each.
1 Answer
Addition polymerization: Monomers add together without loss of any byproduct. Requires C=C double bonds.
$$n\,CH_2=CH_2 \xrightarrow{catalyst} (-CH_2-CH_2-)_n$$
$$(Polyethylene)$$
Condensation polymerization: Monomers react with loss of small molecules (H₂O, HCl, etc.). Requires two different functional groups.
$$n\,HO-R-OH + n\,HOOC-R'-COOH \rightarrow (-O-R-OOC-R'-CO-)_n + n\,H_2O$$
$$e.g., Nylon-6,6 (from hexamethylenediamine + adipic acid)$$