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Using molecular orbital theory, determine the bond order and magnetic property of O₂ — JEE Chemistry

ABAditi Banerjee · 12 Asked 2mo ago 897 views 1 answer

Using molecular orbital theory, determine the bond order and magnetic property of $O_2$.

1 Answer

VAVidaara Admin ✓ Vidaara Team ✓ Accepted · 2mo ago ▲ 7

Total electrons in $O_2$ = 16. MO configuration:

$$(\sigma_{1s})^2(\sigma^*_{1s})^2(\sigma_{2s})^2(\sigma^*_{2s})^2(\sigma_{2p})^2(\pi_{2p})^4(\pi^*_{2p})^2$$

$$Bond Order = \frac{N_b - N_a}{2} = \frac{10 - 6}{2} = 2$$

The two electrons in $\pi^*_{2p}$ orbitals are unpaired (by Hund's rule):

$$O_2 is paramagnetic$$

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Discussion (4)

VC
This finally made it click for me — thank you!
Varun Choudhary · 2mo ago
T
This finally made it click for me — thank you!
TharushiFernando19 · 2mo ago
M
I solved it a slightly different way and got the same answer, good sign.
MasonBrooks15 · 2mo ago
RJ
How do we know the approximation is valid here?
Rahul Joshi · 2mo ago
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