A random variable $X$ assigns a number to each outcome of an experiment (e.g. the number of heads in two tosses). A probability distribution lists each value $x_i$ with its probability $p_i=P(X=x_i)$.
A valid distribution
Every $p_i\ge0$ and $\displaystyle\sum_i p_i=1$. This normalisation condition is the first check (and a frequent "find $k$" question).
Mean (expectation)
The mean or expected value is the probability-weighted average:
$$E(X)=\mu=\sum_i x_i\,p_i.$$
Variance
The variance measures spread:
$$\operatorname{Var}(X)=\sum_i x_i^2 p_i-\mu^2,\qquad \text{SD}=\sqrt{\operatorname{Var}(X)}.$$